Anthranilic Acid as a Spectrophotometric Reagent for the Determination of Vanadium in Presence of 0-Phenanthroline

Authors(1) :-Dilip Kumar

A review of the photometric methods reveals that the complexation reaction between vanadium (IV) and anthranilic acid in presence of o-phenanthroline has not been exploited analytically. The complex of vanadiuin (iv) can be extracted into different solvents. Among the solvents tested, isoamyl alcohol was found to be suitable extractant which extracts the complex conveniently from slightly acidic solutions. An analytical method is proposed for the spectrophotometric determination of vanadium after extracting vanadium(IV)-anthranilic acid-o-phenanthroline complex in isoamyl alcohol. The advantages of the method are its simplicity, selectivity and rapidity of determination without the use of any catalyst.

Authors and Affiliations

Dilip Kumar
Chemistry Department, Kamla Nehru Post Graduat College, Tejgaon, Raebareli (U.P.)

Determination, Vanadium, Presence, 0-Phenanthroline, Anthranilic, Reagent

  1. P. Jов, Ann Chem. Phys., 1928, 9, 113.
  2. H. KOHARU, N. ISHIBASHI and Y. Ito, Bunseki Kagaku 1967, 16. 315 (Chem Abstr., 1967, 67, 39897), S. P MATHUR, V. P. MEHTA, C.S. BHANDARI and N. C. SOGANI An. Quim, 1978,74, 1568 (Chem. Abstr., 1979, 91, 32318), E B SANDELI, "Colorimetric Determination of Traces of Metals. 3rd ed., Interscience, New York, 1959, p. 934, T M. MIRZAKASIMOV, K RAKHMATVILAEV and S.T. TALIPOV, U2h. Khin Zh 1970 14, 15, A 1 BUSEV and Z. P. KARYAKINA, Zh Anal. Khun 1967, 20, 1506 (Chem. Abstr., 1968, 68 35599), N.RS GUPTA and D. B. S GUPTA, J. Indian Chem. Soc., 1973. 50, 112. Κ. PAUL and V. K. GUPTA J. Indian Chem. Soc., 1981, 58, 440, A. SHAHID, 11 A. SHAMUL, C. PRAKASH and R. SONI, Analyst (London) 1988, 113, 1561.
  3. A. L. VOGEL, "A Text Book of Quantitative Inorganic Analysis" Longman. London. 1961. p. 309.

Publication Details

Published in : Volume 4 | Issue 4 | July-August 2021
Date of Publication : 2021-07-18
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 99-101
Manuscript Number : GISRRJ214416
Publisher : Technoscience Academy

ISSN : 2582-0095

Cite This Article :

Dilip Kumar, "Anthranilic Acid as a Spectrophotometric Reagent for the Determination of Vanadium in Presence of 0-Phenanthroline", Gyanshauryam, International Scientific Refereed Research Journal (GISRRJ), ISSN : 2582-0095, Volume 4, Issue 4, pp.99-101, July-August.2021
URL : https://gisrrj.com/GISRRJ214416

Article Preview